VC含量对原位生成WC增强Ni基涂层组织及性能的影响

Effect of VC content on microstructure and properties of Ni-based coatings enhanced by WC in situ

  • 摘要: 为了研究VC作为晶粒生长抑制剂对原位生成WC增强镍基涂层的影响,在H13钢表面分别制备了VC含量为0.1%、1.5%、2%的WC增强镍基涂层。熔覆试样经过切割、磨抛、腐蚀处理后,分别采用扫描电镜(SEM)、X射线衍射仪(XRD)、能谱仪(EDS)、显微硬度计、摩擦磨损试验机进行组织、物相、硬度、摩擦磨损性能的分析和测试。结果表明,VC抑制WC颗粒生长的效果显著。随着VC含量的增多,WC颗粒逐渐细化、涂层组织均匀细密。VC抑制剂减缓WC溶解-析出过程以及降低WC表面能是抑制WC晶粒生长的重要原因。随着VC的加入,WC硬质相的生成被抑制,含钒物质增多。WC增强镍基涂层的硬度随VC含量的增加而提高,但当VC含量大于1.5%时,涂层杂质相增多,WC含量减少而导致涂层硬度下降。当VC含量为1.5%时,能有效细化晶粒,提高涂层硬度。添加VC抑制剂的WC增强镍基涂层摩擦磨损性能更优,磨损机理主要为粘着磨损、脆性剥落和磨粒磨损。

     

    Abstract: In order to investigate the effect of VC as a grain growth inhibitor on the in-situ generation of WC-reinforced nickel-based coatings, WC-reinforced nickel-based coatings with VC contents of 0.1%, 1.5% and 2% were prepared on the surface of H13 steel. After cutting, grinding and polishing, and corrosion treatment, the molten specimens were analysed and tested by scanning electron microscopy (SEM), X-ray diffractometer (XRD), energy spectrometer (EDS), micro hardness tester, and friction wear tester for the analysis of tissue, physical phase, hardness, and friction wear properties, respectively. The results show that VC inhibits the growth of WC particles significantly. As the VC content increased, the WC particles were gradually refined and the coating was homogeneous and dense; the VC inhibitor slowed down the dissolution-precipitation process of WC and reduced the surface energy of WC, which were important reasons for the inhibition of WC grain growth. With the addition of VC, the production of WC hard phases is inhibited and the vanadium containing material increases. The hardness of WC-enhanced nickel-based coatings increases with the increase in VC content, but when the VC content is greater than 1.5%, the impurity phase of the coating increases and the WC content decreases, resulting in a decrease in the hardness of the coating. When the VC content is 1.5%, it can effectively refine the grain and improve the hardness of the coating. The friction wear performance of WC-enhanced nickel-based coatings with VC inhibitor is better, and the wear mechanism is mainly adhesive wear, brittle spalling and abrasive wear.

     

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